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Coordination Chemistry Advanced

JEE Chemistry • 10 questions • Free on ExamBattle

Practice Questions

  1. Q1

    According to Crystal Field Theory, the splitting of d-orbitals in an octahedral field gives:

    • A. All 5 orbitals at same energy
    • B. t₂g (lower) and eg (higher) sets
    • C. eg (lower) and t₂g (higher) sets
    • D. 3 sets of orbitals
  2. Q2

    Which of the following complexes is diamagnetic?

    • A. [Fe(H₂O)₆]²⁺
    • B. [Co(NH₃)₆]³⁺
    • C. [CuCl₄]²⁻
    • D. [Mn(H₂O)₆]²⁺
  3. Q3

    Geometric (cis-trans) isomerism is most commonly observed in:

    • A. Tetrahedral complexes
    • B. Square planar and octahedral complexes
    • C. Linear complexes
    • D. Trigonal planar complexes
  4. Q4

    In the spectrochemical series, the correct order of field strength is:

    • A. CN⁻ < NH₃ < H₂O < Cl⁻
    • B. I⁻ < Cl⁻ < H₂O < NH₃ < CN⁻
    • C. CN⁻ < Cl⁻ < NH₃ < H₂O
    • D. H₂O < Cl⁻ < NH₃ < CN⁻
  5. Q5

    The EAN (effective atomic number) rule was proposed by:

    • A. Werner
    • B. Sidgwick
    • C. Pauling
    • D. Bethe
  6. Q6

    The CFSE (crystal field stabilization energy) for d⁵ high spin octahedral complex is:

    • A. −2.0 Δ₀
    • B. 0
    • C. −0.4 Δ₀
    • D. −2.4 Δ₀

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